منابع مشابه
Mechanism of oxidation of nitroethane by glucose oxidase.
The oxidation of nitroethane by glucose oxidase has been studied in detail and compared to the analogous reaction catalyzed by n-amino acid oxidase and to the behavior of sugar substrates of glucose oxidase. The overall stoichiometry of the reaction is nonintegral and incompletely understood. Although the major products are nitrite, acetaldehyde (P), and hydrogen peroxide, small amounts of nitr...
متن کاملMechanism of interference by uric acid in the glucose oxidase-peroxidase method for serum glucose.
A number of chromogens have been proposed in the past. In the glucose oxidase “GOD-Perid”1 method, the subject of study in this paper, ABTS is used as the chromogen (6). Unfortunately, the glucose oxmdase methods are not free of interference from other substances, uric acid being one. Here, I examine each reaction step of the GOD-Perid method, discuss possible mechanisms of interference by uric...
متن کاملQM/MM Study on the Mechanism of Aminophenol Oxidation by Functionalized β-Cyclodextrin as Oxidase Nanomimic
In this study, functionalized β-cyclodextrin (β-CD) by aldehyde group was investigated as an oxidase enzyme mimic for the amino phenol oxidation. All calculations were performed by GAUSSIAN 09 package using two layers ONIOM method at the ONIOM (MPW1PW91/6-311++G(d,p)/UFF) level. In the first step, H2O2 is encapsulated in the hydrophobic cavity. In the second step, H2<...
متن کاملThe obtain optimum production conditions for Glucose Oxidase biosensor using software Qualtek-4
The Glucose Oxidase (Gox) electrochemical sensors were used to detect a little amount of glucose. In this paper, the pure platinum plate (length of 5 cm and a width of 3 mm), the Ag/AgCl electrode and platinum electrode (diameter of 1 mm) were applied as a working electrode (W.E), reference electrode and auxiliary electrode sequential. Factors measured, glucose concentration and pH is Phosphate...
متن کاملThe obtain optimum production conditions for Glucose Oxidase biosensor using software Qualtek-4
The Glucose Oxidase (Gox) electrochemical sensors were used to detect a little amount of glucose. In this paper, the pure platinum plate (length of 5 cm and a width of 3 mm), the Ag/AgCl electrode and platinum electrode (diameter of 1 mm) were applied as a working electrode (W.E), reference electrode and auxiliary electrode sequential. Factors measured, glucose concentration and pH is Phosphate...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1971
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(18)62246-x